Ionic solutions are known to be electrolytes due to the presence of free ions. Covalent solutions are non-electrolytes hence the decrease the conductivity of the ionic solutions.
Electrolytes are solutions that conduct electricity. The charge carriers in solution are ions. These ions are mobile. Covalent substances are molecular in nature. They do not contain ions hence they do not give ions when dissolved in water.
The conductivity of ionic solutions owes to the presence of ions in solution. The higher the concentration of ions in solution, the greater the conductivity of the solution. When covalent substances are mixed with ionic solutions, the concentration of ions decreases and the conductivity of the solution decreases.
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