Respuesta :
The anode compartment contains [SO2-4] with a concentration of 1.30 m, this is in equilibrium with PbSO4 (s). The dissociation of PbSO4 is:
PbSO4 + H2O ---> Pb 2+ + SO4 2-
The Ksp of PbSO4:
Ksp = [Pb2+] [SO4-2]
PbSO4 + H2O ---> Pb 2+ + SO4 2-
The Ksp of PbSO4:
Ksp = [Pb2+] [SO4-2]
Answer:
The solubility product lead sulfate at anode is 1.69.
Explanation:
[tex]PbSO_4\rightleftharpoons Pb^{2+}+SO_4^{2-}[/tex]
S S
Concentration of sulfate ion at anode:
[tex][SO_4^{2-}]=S=1.30 M[/tex]
1 mole of lead sulfate dissociates into 1 mol of lead ion and 1 mole of sulfate ion.So.
[tex]SO_4^{2-}=[Pb^{2+}]=S[/tex]
The solubility product of the lead sulfate is:
[tex]K_{sp}=S\times S=S^2=(1.30 M)^2=1.69[/tex]
The solubility product lead sulfate at anode is 1.69.