The new deal political coalition consisted of all the following except big business owners. Thus, option fourth is correct.
Coalition refers to grouping of the two different association into one single group. It includes the merger into one body or mass in terms of biology.
In a political sense, it is a combination or alliance, especially a transient one between people, factions, nations, etc. New deal political coalition consisted of the groups like African Americans, diverse urban populations, Southern whites, and unionized industrial workers.
Therefore, it can be concluded that Except large corporate owners, all the following comprised the new deal political coalition. Hence, option fourth is correct.
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List of options:-