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A student ran the following reaction in the laboratory at 1080 K: 2SO3(g) 2SO2(g) + O2(g) When she introduced SO3(g) at a pressure of 0.948 atm into a 1.00 L evacuated container, she found the equilibrium partial pressure of SO3(g) to be 0.369 atm. Calculate the equilibrium constant, Kp, she obtained for this reaction. Kp =

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Answer:

0.078

Explanation:

The equation is :

                [tex]$2SO_3 (g) \ \ \ \Leftrightarrow \ \ \ 2 SO_2(g) \ \ \ + \ \ \ O_2(g)$[/tex]

Initial         0.948                  -----                   ----

Change      -2x                     +2x                  +x

Final          0.369                  2x                    x

So the total pressure must reman same = 0.948

And the total pressure = partial pressure of all gases

0.948   =   ( 0.369 + 2x + x )

0.948  =  0.369 + 3x

[tex]$x=\frac{0.579}{3}$[/tex]

  = 0.193 atm

So the partial pressure of [tex]$SO_2$[/tex]  = 0.193 x 2

                                                   = 0.386 atm

Partial pressure of [tex]$O_2$[/tex]  =  0.193 atm

Therefore,

[tex]$k_p=\frac{(P_{SO_2})^2(P_{O_2})^}{(P_{SO_3})^2}$[/tex]

    [tex]$=\frac{(0.386)^2(0.193)}{0.369}$[/tex]

    = 0.078

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