Show your reasoning in describing what would be the effect on the calculated equilibrium constant for each of the following mistakes.
1. Your buret was not rinsed with NaNCS solution before use and still contained traces of distilled water.
2. The spectrophotometer was set well-past infinite absorbance upon calibration with the sample holder empty.

There is a mistake in the value of equilibrium constant if the burette contains traces of distilled water because the water will be present in the solution from which equilibrium constant is calculated. The spectrophotometer did not give the correct reading because its calibration is incorrect. If we want to gain correct readings from the spectrophotometer, we must have to calibrate the instrument correctly.

nikitarahangdaleVT nikitarahangdaleVT · Answer 2 · 2022-03-11T06:49:50+01:00

Incorrect value of equilibrium constant is obtained.

What is equilibrium constant?

Equilibrium constant of any reaction tells about the relative ration of the concentration of products to the reactants.

Value of equilibrium constant can be calculated in the aqueous medium where concentration of water also present. If we don't rinse the burette with the reaction solution then the already present traces of water affect the concentration of water during the calculation of equilibrium constant.

As the absorbance of any solution is also directly proportional to the concentration, so if the spectrometer is not calibrated accurately then incorrect value of absorbance also affects the value of equilibrium constant.

Hence, we get incorrect value of equilibrium constant for each of the given mistakes.

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