The procedure that would most likely help determine a chemical property of the substance is B. exposing it to a flame to see if it catches on fire.
It should be noted that the heating of the solid to find the temperature at which it melts or hitting it with a hammer to determine if it breaks or bends cannot be used to determine the chemical property of the solid.
The exposure of the unknown solid to a flame to see if it catches on fire can be vital in knowing the chemical property of the solid.
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