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At 250ºC, the equilibrium constant Kp for the reaction PCl5(g) PCl3(g) + Cl2(g) is 1.80. Sufficient PCl5 is put into a reaction vessel to give an initial pressure of 2.74 atm at 250ºC. Calculate the pressure of PCl5 after the system has reached equilibrium

Respuesta :

Answer:

1.2 atm is the pressure of  [tex]PCl_5[/tex] after the system has reached equilibrium.

Explanation:

Initial pressure of the [tex]PCl_5[/tex] =2.74 atm

The value of the equilibrium constant = [tex]K_p=1.80[/tex]

[tex]PCl_5(g)\rightleftharpoons PCl_3(g) + Cl_2(g)[/tex]

Initially

2.74 atm      0       0

At equilibrium

(2.74-p)      p         p

The expression of an equilibrium constant can be given as:

[tex]K_p=\frac{p_{PCl_3}\times p_{Cl_2}}{p_{PCl_5}}[/tex]

[tex]1.80=\frac{p\times p}{(2.74-p)}[/tex]

Solving for p:

p = 1.50 atm

Pressure of the [tex]PCl_5[/tex] at equilibrium :

= (2.74-p) atm  = 2.74 - 1.50 atm = 1.2 atm

1.2 atm is the pressure of  [tex]PCl_5[/tex] after the system has reached equilibrium.

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