The temperature of an ideal gas in a sealed 0.5-m3 rigid container is reduced from 350 K to 270 K. The final pressure of the gas is 70 kPa. The molar heat capacity at constant volume of the gas is 28.0 J/mol · K. The heat absorbed by the gas is closest to_________

Respuesta :

Answer :  The heat absorbed by the gas is closest to 34.9 kJ

Explanation :

First we have to calculate the moles of gas.

Using ideal gas equation:

[tex]PV=nRT[/tex]

where,

P = Pressure of gas = 70 kPa  = 70000 Pa

V = Volume of gas = [tex]0.5m^3[/tex]

n = number of moles = ?

R = Gas constant = [tex]8.314m^3Pa/mol.K[/tex]

T = Temperature of gas = [tex]270K[/tex]

Putting values in above equation, we get:

[tex]70000Pa\times 0.5m^3=n\times (8.314m^3Pa/mol.K)\times 270K[/tex]

[tex]n=15.59mol[/tex]

Heat released at constant volume is known as internal energy.

The formula used for change in internal energy of the gas is:

[tex]\Delta Q=\Delta U\\\\\Delta U=nC_v\Delta T\\\\\Delta Q=nC_v(T_2-T_1)[/tex]

where,

[tex]\Delta Q[/tex] = heat at constant volume = ?  

[tex]\Delta U[/tex] = change in internal energy

n = number of moles of gas = 15.59 moles

[tex]C_v[/tex] = heat capacity at constant volume gas = 28.0 J/mol.K

[tex]T_1[/tex] = initial temperature = 350 K

[tex]T_2[/tex] = final temperature = 270 K

Now put all the given values in the above formula, we get:

[tex]\Delta Q=nC_v(T_2-T_1)[/tex]

[tex]\Delta Q=(15.59moles)\times (28.0J/mol.K)\times (270-350)K[/tex]

[tex]\Delta Q=-34921.6J=-34.9kJ[/tex]

Thus, the heat absorbed by the gas is closest to 34.9 kJ

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