The specific heat capacity of silver is 0.235 J/g ∙ K. Its melting point is 962 °C, and its enthalpy of fusion is 11.3 kJ/mol. What quantity of energy, in joules, is required to change 9.70 g of silver from a solid at 25 °C to a liquid at 962 °C?

Respuesta :

Answer: The total heat required for the conversion process is 1228.5 J

Explanation:

The processes involved in the given problem are:  

[tex]1.)Ag(s)(25^oC,298K)\rightarrow Ag(s)(962^oC,1235K)\\2.)Ag(s)(962^oC,1235K)\rightarrow Ag(l)(962^oC,1235K)[/tex]

  • For process 1:

To calculate the amount of heat absorbed, we use the equation:

[tex]q_1=m\times C_{p,l}\times (T_{2}-T_{1})[/tex]

where,

[tex]q_1[/tex] = amount of heat absorbed = ?

[tex]C_{p,s}[/tex] = specific heat capacity = 0.235 J/g.K

m = mass of silver = 9.70 g

[tex]T_2[/tex] = final temperature = 1235 K

[tex]T_1[/tex] = initial temperature = 298 K

Putting all the values in above equation, we get:

[tex]q_1=9.70g\times 0.235J/g.K\times (1235-298)K=213.6J[/tex]

  • For process 2:

To calculate the amount of heat released, we use the equation:

[tex]q_2=m\times L_f[/tex]

where,

[tex]q_2[/tex] = amount of heat absorbed = ?

m = mass of silver = 9.70 g

[tex]L_f[/tex] = latent heat of fusion = 11.3 kJ/mol = [tex]\frac{11300J/mol}{108g/mol}=104.63J/g[/tex]   (Conversion factor:  1 kJ = 1000 J; Molar mass of silver = 108 g/mol)

Putting all the values in above equation, we get:

[tex]q_2=9.70g\times 104.63J/g=1014.9J[/tex]

Total heat required for the conversion = [tex]q_1+q_2[/tex]

Total heat required for the conversion = [tex][213.6+1014.9]J=1228.5J[/tex]

Hence, the total heat required for the conversion process is 1228.5 J

ACCESS MORE
ACCESS MORE
ACCESS MORE
ACCESS MORE