Respuesta :
Answer:
The first-order biodegradation rate constant that must be reached to achieve the treatment goal is
k = 0.003456 /day
Explanation:
Each of the lagoon can be treated as a continuously stirred tank reactor.
Let C₀ represent the initial concentration of the biodegradable organic material = 100 g/L = 100 g/m³
Let C₁ be the concentration of biodegradable organic material that leaves the first lagoon and entering the second lagoon.
Let C₂ be the concentration of biodegradable organic material leaving the second lagoon = 20 mg/L = 20 g/m³
Let the rate constant be k
Let V be the volume of each of the lagoons = 5 hectares × 1 m = 50000 × 1 = 50000 m³
Let F₀ be the flowrate of influent into the first lagoon = 8640 m³/day
Let F₁ be the flowrate of outlet from lagoon 1 and influent into lagoon 2.
Let F₂ be the flowrate of outlet from lagoon 2.
Since the volumes of the lagoon (reactors) are constant, F₀ = F₁ = F₂ = 8640 m³/day
The performance equation for a CSTR with a first order reaction going on for lagoon 1 is
(kC₀V/F₀) = (C₀ - C₁)/C₁
Make C₁ the subject of formula
C₁ = (F₀C₀)/(kC₀V + F₀) = (8640)(100)/[(k×100×50000) + 8640]
C₁ = 864000/(5000000k + 8640)
For the 2nd lagoon, performance equation is
(kC₁V/F₁) = (C₁ - C₂)/C₂
Make C₁ the subject of formula once more
C₁ = - F₁ C₂/(kC₂V - F₁)
F₁ = 8640 m³/day, V = 50000 m³, C₂ = 20 mg/L = 20 g/m³
C₁ = (-8640 × 20)/(k×20×50000 - 8640)
C₁ = - 172800/(1000000k - 8640)
Equating the C1 in both equations to each others
864000/(5000000k + 8640) = -172800/(1000000k - 8640)
864000 (1000000k - 8640) = - 172800(5000000k + 8640)
864 (1000k - 8.64) = - 172.8 (5000k + 8.64)
864000k - 7464.96 = - 864000k - 1492.992
864000k + 864000k = 7464.96 - 1492.992
1728000k = 5971.968
k = 0.003456 /day.
