Acetic acid has a Ka of 1.8×10−5. Three acetic acid/acetate buffer solutions, A, B, and C, were made using varying concentrations:______[acetic acid] ten times greater than [acetate],[acetate] ten times greater than [acetic acid], and[acetate]=[acetic acid].Match each buffer to the expected pH.pH = 3.74 ; pH = 4.74 ; pH = 5.74

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Answer:

A: pH = 3.74

B: pH = 5.74

C: pH = 4.74

Explanation:

According to the Henderson-Hasselbach equation for buffers, we know that [tex]pH = pK_a + log(\frac{[A^-]}{[HA]})[/tex]. Firstly, let's find the [tex]pK_a[/tex] value:

[tex]pK_a = -log(K_a) = -log(1.8\cdot 10^-5) = 4.74[/tex]

Now, for buffer A:

[tex]\frac{[A^-]}{[HA]}=\frac{[CH_3COO^-]}{[CH_3COOH]}=\frac{1}{10}[/tex]

This means:

[tex]pH = 4.74 + log(\frac{1}{10}) = 3.74[/tex]

Similarly, for buffer B:

[tex]\frac{[A^-]}{[HA]}=\frac{[CH_3COO^-]}{[CH_3COOH]}=\frac{10}{1}[/tex]

This means:

[tex]pH = 4.74 + log(\frac{10}{1}) = 5.74[/tex]

Similarly, for buffer C:

[tex]\frac{[A^-]}{[HA]}=\frac{[CH_3COO^-]}{[CH_3COOH]}=\frac{1}{1}[/tex]

This means:

[tex]pH = 4.74 + log(\frac{1}{1}) = 4.74[/tex]

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