180 degrees.
Each cyanate ion [tex]\text{OCN}^{-}[/tex] contains one carbon atom, one oxygen atom, and one nitrogen atom. The ion carries a charge of negative one.
The ion would demand [tex]2 + 3 + 4 - 1 = 8[/tex] extra electrons to ensure a complete octet for each of its atom. It would do so by forming [tex]8/2 = 4[/tex] covalent bonds.
There are two possible configurations:
Either way, the central carbon atom would end up with two electron domains and no lone pairs. By the VSEPR theory, the molecule would end up with a linear geometry. It would thus have an O-C-N bond angle of 180 degrees.